On April 8, at the First Session, with 489/489 delegates participating in the vote in favor, the 16th National Assembly passed a Resolution on the structure of the number of Government members for the 2026-2031 term.
Accordingly, the structure of the number of Government members for the 2026-2031 term includes 23 members: Prime Minister; 6 Deputy Prime Ministers; 14 Ministers of Ministries: National Defense; Public Security; Foreign Affairs; Home Affairs; Justice; Finance; Industry and Trade; Agriculture and Environment; Construction; Culture, Sports and Tourism; Science and Technology; Education and Training; Health; Ethnic Minorities and Religion.
3 Heads of ministerial-level agencies: Governor of the State Bank of Vietnam; Inspector General of the Government; Minister, Chairman of the Government Office.
With 481/481 National Assembly deputies participating in the vote in favor, the 16th National Assembly voted to approve the Resolution approving the Prime Minister's proposal on the appointment of Ministers and other members of the Government for the 2026-2031 term.

According to the Resolution just passed, the Government for the 2026-2031 term has 17 Ministers and heads of sectors, including the following:
| 1 | Phan Van Giang | General, Member of the Politburo, Deputy Prime Minister cum Minister of National Defense |
| 2 | Luong Tam Quang | General, Member of the Politburo, Minister of Public Security |
| 3 | Le Hoai Trung | Politburo Member, Minister of Foreign Affairs |
| 4 | By Thanh Binh | Member of the Party Central Committee, Minister of Home Affairs |
| 5 | Hoang Thanh Tung | Member of the Party Central Committee, Minister of Justice |
| 6 | Ngo Van Tuan | Member of the Party Central Committee, Minister of Finance |
| 7 | Le Manh Hung | Member of the Party Central Committee, Minister of Industry and Trade |
| 8 | Trinh Viet Hung | Member of the Party Central Committee, Minister of Agriculture and Environment |
| 9 | Tran Hong Minh | Member of the Party Central Committee, Minister of Construction |
| 10 | Lam Thi Phuong Thanh | Member of the Party Central Committee, Minister of Culture, Sports and Tourism |
| 11 | Vu Hai Quan | Member of the Party Central Committee, Minister of Science and Technology |
| 12 | Hoang Minh Son | Member of the Party Central Committee, Minister of Education and Training |
| 13 | Dao Hong Lan | Member of the Party Central Committee, Minister of Health |
| 14 | Nguyen Dinh Khang | Member of the Party Central Committee, Minister of Ethnic Minorities and Religious Affairs |
| 15 | Dang Xuan Phong | Member of the Party Central Committee, Minister, Head of the Government Office |
| 16 | Pham Duc An | Member of the Party Central Committee, Governor of the State Bank of Vietnam |
| 17 | Nguyen Quoc Doan | Member of the Party Central Committee, Inspector General of the Government |
Previously, the National Assembly voted to approve the Resolution approving the Prime Minister's proposal on the appointment of Deputy Prime Ministers for the 2026-2031 term, including Mr./Ms.: Pham Gia Tuc, Phan Van Giang, Pham Thi Thanh Tra, Ho Quoc Dung, Nguyen Van Thang, Le Tien Chau.
Among the Deputy Prime Ministers, General Phan Van Giang was also approved to be appointed Minister of National Defense.